IB Chemistry HL S2.4 From models to materials questions

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Question 1

Multiple choiceEasy1 mark

The electronegativity values, χ, of the elements in four binary compounds are shown.

ElementMgONaClCaFC
χ1.23.50.93.01.04.02.5

Which compound is predicted to have the greatest ionic contribution to its bonding?

Show answer and explanation

Answer: C [1]. A larger electronegativity difference indicates a greater ionic contribution. The differences are MgO: |3.5 − 1.2| = 2.3; NaCl: |3.0 − 0.9| = 2.1; CaF₂: |4.0 − 1.0| = 3.0; CF₄: |4.0 − 2.5| = 1.5. CaF₂ has the largest difference.

A: MgO has a substantial difference, but 2.3 is less than 3.0.
B: NaCl is ionic, but its difference of 2.1 is less than 3.0.
D: A high mean electronegativity alone does not indicate a greater covalent contribution; CF₄ is less ionic here because its electronegativity difference is smaller.

Remember: electronegativity difference indicates the ionic contribution to bonding.

Total: [1]

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