IB Chemistry SL R1.2 Energy cycles in reactions questions

Exam-style multiple choice and written questions with full markschemes. Check multiple choice answers straight away, or type, photograph or draw a written answer and get it marked.

Question 1

Multiple choiceEasy1 mark

An exothermic reaction is carried out with and without a catalyst. The catalyst provides an alternative pathway, while the reactants and products are unchanged. How does ΔH\Delta H compare?

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Answer: B. Enthalpy change depends on the enthalpies of the initial and final states, not on the pathway. Since those states are unchanged, ΔH\Delta H is unchanged.

A: confuses the catalyst’s effect on activation energy with making the reaction enthalpy less negative.
C: assumes the alternative pathway changes the energy released, although the initial and final states are unchanged.
D: treats an alternative pathway as the reverse reaction; reversing a reaction reverses the sign of ΔH\Delta H

Remember: Hess’s law makes ΔH\Delta H pathway-independent.