Question 1

Paper 2Medium6 marks

Chlorine reacts with propane when irradiated with ultraviolet (UV) light. Figure 1 shows the displayed structural formula of propane.

CCCHHHHHHHH
(a)

Determine the number of different monochlorinated structural isomers that can form from propane.

[1]
(b)

Write the equation for the initiation step, using single-barbed arrows to show the movement of electrons.

[2]
(c)

For the formation of 2-chloropropane:

(i)

Write the first propagation equation, in which a hydrogen atom is transferred from propane to a chlorine radical.

[1]
(ii)

Using the propan-2-yl radical, CH₃CH•CH₃, write the second propagation equation.

[1]
(d)

Write one equation for a termination step in this chain reaction.

[1]

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