Question 1

Paper 2Medium7 marks

The wavelength corresponding to the limit of convergence at higher frequency in the emission spectrum of gaseous element Q is 285.7 nm285.7\ \mathrm{nm}

A database gives the following successive ionization energies for Q.

Ionization energyValue / kJ mol−1\mathrm{kJ\,mol^{-1}}
First419
Second3052
Third4420
Fourth5877
(a)

Calculate the first ionization energy of Q in kJ mol−1\mathrm{kJ\,mol^{-1}} using the data booklet. Give your answer to three significant figures.

[3]
(b)

Use your result from (a) and the successive ionization energy data.

(i)

State whether your result from (a) agrees with the database value for the first ionization energy to three significant figures.

[1]
(ii)

Deduce the group of Q, explaining your deduction using the successive ionization energy data.

[3]

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